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Boron - Friend or Foe?

Unless you are old enough to remember early TV shows sponsored by 20 MULE TEAM BORAX, there’s a good chance that you have never heard of boron.

As a close cousin to carbon on the Periodic Table of Elements, boron is a very lightweight element that appears worldwide on land and in the oceans in various concentrations. Scientists have not universally agreed whether boron originally comes from the sea and aerosols to land or dissolves from land sources and finds its way to the sea via surface water discharge. It doesn’t exist naturally as the element boron, but rather as solid boric acid (H3BO3) or as borax (Na2[B4O5(OH)4].8H2O). Both forms are readily water-soluble, so boron can also be found in well water supplies because it dissolves in rainwater and percolates through the soil into aquifers. Aquifers in contact with borax mineral deposits as well as those with seawater intrusion will also have elevated boron levels.

Commercial uses for boron compounds range from improving rare earth magnets for electric vehicle batteries to a detergent additive. As a detergent additive, borax (see above formula) actually precipitates the calcium (hardness) and leaves the sodium in the water. This process is similar to physical water treatment non-salt water softeners which are rapidly replacing salt-type water softeners with devices that use zero water and discharge zero pollutants to drain.

Both the medical and the agricultural communities refer to boron as a micronutrient. In this status, some presence of boron is vital to human and animal development as well as plant health. For humans and animals, boron works in concert with vitamin D to assist the assimilation of calcium which is necessary for bone, tooth, and brain tissue growth and maintenance. Its importance is so much so that those with a deficiency of vitamin D, maybe due to a lack of sun exposure, often take vitamin d drops to maintain this balance. Ideally, humans will ingest approximately 1 mg of boron daily through the consumption of green, leafy vegetables, drinking water, and non-citrus fruits. Above 3 milligrams daily some health issues may arise including diarrhea, vomiting, indigestion, and headaches. Fatal doses are in the 15,000 to 20,000 range. Drinking water has the potential of raising the boron intake above healthy levels, thus the USEPA sets a non-mandated limit of 2 (children) to 3 (adults) milligrams per liter; the World Health Organization limit is 2.4 mg/l, and states including California set an upper limit of 1 mg/l.

In plant growth, the effective uptake and use of phosphorus and calcium are assured with only trace amounts of boron available at the roots. This presence follows Liebig’s Law of Minimums meaning that in the absence of boron, plants will not absorb phosphorus or calcium at sufficient levels regardless of how much is applied. Unlike standard human upper tolerance levels, damages to plants begin at in-the-water levels of >0.5 mg/l for blackberries and cannabis to >15 mg/l for asparagus.

If there is insufficient boron present, there are readily available supplements for humans, animals and crops. Excess boron, especially in water, is an entirely different issue. The go-to technology of reverse osmosis simply doesn’t work. The low energy of the boron ion negates ion diffusion upon which osmosis membrane rejection depends upon. Likewise, traditional ion exchange resins fail to remove boron regardless of what regenerant chemical is used. Recently, an adsorption filter medium selective to boron and not interfered by other ions has become available. Devices are available as disposable point-of-use cartridges for point-of-use drinking water applications as well as regenerating small and large pressure vessels for agricultural applications. Typically, a bit pricey, but proven to be effective. The agricultural versions often mean having a viable business or not.

Irrigation Water Conditioning Opportunities

According to the U.S. Department of the Interior USGS division, 70% of all fresh water worldwide is consumed in growing crops. Some countries such as Israel, Saudi Arabia and states like California, Florida and the Dakotas, have higher percentages. With drought conditions predicted in 2021 and 2022 for much of the world and the western US in particular, treatment opportunities for water professionals should be significant.

The problem associated with much of the accessible irrigation water is brackishness that slows or stops water from adequately following the xylems (capillary network) in plants. This results in the need to over water and if not over watered, plants and their nutritional value are significantly reduced. Needless to say, this excess water is subtracted from available supplies for homes and industry.

Historically, the brackishness is countered by continued over watering (until sources are exhausted) or by employing R.O. systems which in addition to high capital and operating costs is counterproductive because of waste streams. Much of the World has found relief by employing magnetic devices especially in Russia, Eastern European countries and Israel where resources are scarce. One of the best university studies is available through Research Gate www.researchgate.net/publication/284724980 “Impact of Magnetic Water on Plant Growth” coauthored by Jaime da Silva of Japan and Judit Dobranszki of Debrecan University in Hungary. Typical reported results document water savings in the 10% range which could ease drought conditions by billions of gallons in the US.

All published effectiveness reports on magnetic water treatment for irrigation come up short on the issue of why the process works, which understandably creates skepticism at a professional level. The answer may be found in a recently published research book by Gerald H. Pollack, PhD Engineering titled The Fourth Phase of Water. Numerous and well-documented experiments on the properties of water were carried out by Dr. Pollack and his research assistants at his laboratory at the University of Washington. His work reveals that energy (infrared and EMF) applied to water causes a particular hexagonal structuring of water molecules while simultaneously releasing hydrogen ions that create hydronium (H 3 O) molecules in close proximity water. Further tests in the book postulate enhanced capillary action and a unique look at why this occurs.

We believe that a magnetic field can be the energy that changes the water structure to that described by Dr. Pollack. As an explanation of this phenomenon, think of how an electrical generator works: In its simplest form, an outside energy source such as an engine or a turbine moves a conductor (wire) in an electro magnetic field which results in movement of electrons in the wire which defines electricity. The quantitive expression of this is FARADAY’S LAW or EMF = v x B x L x sin A where:

EMF = Electro Motive (or Magnetic) Force or Volts (V) output

v = the velocity of the conductor in meters/sec. (Velocity is a vector which must include direction as opposed to speed which doesn’t require a directional component.)

B = magnetic field strength in Gauss units as opposed to Tesla units

L = length of conductor in meters

A = the angularity of the conductor relative to the magnetic field which defines velocity vs. speed. It is 90 0 in a pipe configuration with magnets on the circumference as most existing systems are constructed. The sin of 90 0 = 1, so it does not affect the voltage value.

In our math modeling of a system, the outside energy to run the “generator” is the water pump feeding the irrigation line, the wire (conductor) is water which of course is conductive unless it is D.I. or distilled water, the velocity is the result of flow rate, length of conductor is the length from in to out of device and field strength is the result of typically permanent magnets along with their type, quantity and placement. By applying the right-hand rule, the positive pole is on the inlet of the device. Knowing the resistance of the water column within the device by either measurement or using a TDS/CONDUCTIVITY CHART resistance can be determined and using OHM’S LAW V=IR with voltage from above I (amps) can be solved for as I = V/R. Finally, we can determine the energy going into the water which is derived from WATT’S LAW P=VI where P = Power in watts, a universal expression of energy. Through algebraic manipulation of ohms law, P in watts can also be expressed as P = I 2 R. Trial calculations show volts, amps and watts in the milli range.

This presentation is an expression of DC (Direct Current) power. Multiple magnet fields will produce a pulsing DC voltage and by axially changing magnetic field polarization from field to field, AC (Alternating Current) power will be produced. Hopefully this presentation will overcome some of the stigma associated with magnets and provide a plausible explanation for their efficacy in agricultural water applications.

We encourage people in the traditional water conditioning industry to align themselves with one of the many suppliers of agricultural magnetic systems. By offering such devices, we believe many millions of gallons of irrigation water can be diverted to residential and commercial uses which is especially important during drought conditions. For further interesting information on water properties, we recommend purchasing and studying Dr. Pollack’s book.

Water Treatment Units for Agriculture

Agriculture demands high water standards

Proper water is critical in many agriculture applications. Animals are very sensitive to water quality and will only drink enough to survive.

The agriculture market is confronting water treatment issues related to an ever-increasing demand for irrigation water, compromised water quality, declining availability and expanded government regulations. The vegetable and fruit processor’s segment of the market also faces water treatment issues and regulations that involve vegetable/fruit washing and waste water recycling.

As for the dairy and CAFO segments of the agricultural producer market, manure storage, treatment, and handling regulation compliance are major issues that need to be addressed. Each of these issues needs to have adequate support to ensure they are meeting the requirements set. This may mean speaking to a metal building contractor for proper storage solutions, as well as keeping up to date with compliance guidelines. Water treatment technologies employed for the agriculture markets include:

  • Filtration
  • Mixing/Aeration
  • Reverse Osmosis

Dime Water, Inc. provides customized water management solutions and project/application-specific integrated water treatment, helping agriculture businesses thrive through reuse and recycling:

  • Nanofiltration Units
  • Sulfate/Nitrate Removal Units

Water sources traditionally used in this field and its applications include surface water, groundwater, properly treated municipal and industrial wastewaters, and liquid manures stored in lagoons onsite large dairy and swine farms. As the commercial agriculture consumes more and more water, both wastewater streams and regulatory requirements increase. To ensure profitability, commercial agriculture operations must reduce water usage, bacteria growth rates and reduce waterborne diseases, among other requirements. Commercial growers looking for the latest technology in horticulture cultivation should check out the products available from Agron – learn more.

Wastewater treatment solutions for agriculture should be chemical-free in order to implement effective wastewater management, which has become one of the cornerstones of running a successful agriculture business. Our equipment delivers cost-effective and chemical-free solutions for the treatment and reuse of large amounts of wastewater generated from agricultural operations. Furthermore, hiring companies like urban-gro to help create a controlled environment agriculture design can better organize the way that they are using the land and water usage.

Wastewater from livestock farms and feedlots for example is highly odorous and toxic, containing high nitrate and phosphorous content, pathogenic bacteria, and antibiotics. Vineyards and wineries require special wastewater treatment, which includes solids removal, bacteria control, membrane biofouling, and pH neutralization. To achieve the correct water treatment solution, it might be worth visiting https://www.veoliawatertech.com/en/expertise/applications/wastewater-treatment, for example. That company should be able to implement a custom-tailored system that should treat any water, making it safe to use again.

Dime Water, Inc. relies on a variety of computer programs to design systems tailored to our client’s specific water supply and application needs. Our technology can solve the most challenging agricultural water treatment challenges and meet the needs of each unique customer.

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